The effect of extracellular polymers (EPS) on the proton adsorption characteristics of the thermophile Bacillus licheniformis S-86     

Janette Tourney  Bryne T. Ngwenya  J.W. Fred Mosselmans  Laurence Tetley  Gregory L. Cowie 《Chemical Geology》2008,247(1-2):1-15

This study investigated proton adsorption to an extracellular polymeric substance (EPS) producing bacterial strain, Bacillus licheniformis S-86, in order to characterise and quantify the contribution made by EPS to cell surface reactivity. Potentiometric titrations were conducted using both untreated cells and cells from which the EPS layer had been extracted. Surface-complexation modelling indicated the presence of four different functional groups in both untreated and EPS-free cells. These sites are assigned to phosphodiester, (pK_a 3.3–3.4), carboxylic (pK_a 5.3–5.4), phosphoryl/ (pK_a 7.4–7.5) and hydroxyl/amine (pK_a 9.9–10.1) type groups. The pK_a values for the four groups were very similar for untreated and EPS-free cells, indicating no qualitative difference in composition, but site concentrations in the untreated cells were statistically found to be significantly higher than those in the EPS-free cells for the pK_a 3.3–3.4 and pK_a 9.9–10.1 sites. Infrared analysis provided supporting evidence that site 2 is carboxylic in nature but did not reveal any difference in IR absorption between the native and EPS-free cells. Dissolved organic carbon (DOC) analysis conducted during this study indicated that DOC release by cells is significant, and that the EPS layer is the major contributor.  相似文献   

梁子湖水体P的季节变化与沉积物P释放初步研究   总被引：4，自引：0，他引：4  

熊汉锋  陈治平  黄世宽  谭启玲  丰民义  王运华 《湿地科学》2006,4(3):174-178

采用分级测定的方法对梁子湖沉积物中无机磷酸盐进行了分析,测定了梁子湖水体P的季节变化,并以室内模拟的方法研究梁子湖沉积物在pH值和温度控制下P的释放特征。研究表明,梁子湖水体P的含量呈明显的季节变化,冬季高,夏季低。沉积物无机磷(P i)中以钙磷(Ca—P)为主(55%~61%),铁磷(Fe—P)次之(28%~33%),铝磷(A l—P)最少(3%~5%)。在梁子湖的入水口和出水口,由于沉积环境影响到P的形态,P的释放明显较湖心高。在试验初期,由于扰动的影响,使得P的释放在第1天比第2天和第3天高,其后P的释放量则迅速增加。温度对P释放影响明显,其具体表现为,30℃时P释放达到峰值的时间比4℃时提前4 d,而且前者峰值比后者高出9倍。pH值对沉积物P释放同样有明显的影响,与正常状态下的湖水条件(pH值为8.5)相比,偏酸(pH值为5.5)和偏碱(pH值为11.5)条件下,P的释放量增加。  相似文献   

Simulating the effect of Nitrogen application on Wheat Yield by linking remotely sensed measurements with wtgrows simulation model     

V. K. Sehgal  C. V. S. Sastri 《Journal of the Indian Society of Remote Sensing》2005,33(2):297-305

A field experiment was conducted on wheat at New Delhi with five treatments of Nitrogen (N) fertilizer application (0, 30, 60, 90 and 120 kgha^-1). Relationship has been established between observed leaf area index (LAI) and remotely sensed vegetation indices. These relationships are inverted and used for predicting LAI from vegetation indices on different days after sowing. The “re-initialization” strategy is implemented in model WTGROWS in which initial conditions of model are changed so that the model simulated LAI match remote sensing predicted LAI. The model performance with re-initialization has been evaluated by comparing the simulated grain yield and total above-ground dry matter (TDM) values with the actual observations. The results show that in-season re-initialization is effective in model course correction by improving the simulated results of yield and TDM for different N treatments even though the model was run with no N stress condition. Model re-initialization at different days shows that the closer is the day of re-initialization to crop anthesis the more effective is model course correction. Also, the treatment showing maximum error in yield simulation without re-initialization shows maximum reduction in error by re-initialization. The approach shows that the remote sensing inputs can substitute for some of the inputs or errors in inputs required by crop models for yield prediction.  相似文献   

长江三峡库区梯田稳定性分析与对策^*──以鄂西秭归县为例   总被引：6，自引：0，他引：6  

蔡强国  张光远 《地理研究》1997,16(1):45-52

三峡库区历史上就是滑坡、崩塌作用强烈的地带,在调查分析秭归县滑坡、崩塌对梯田稳定性的影响的基础上,探讨了四种不稳定梯田培坎的特征、性质和现状,提出了利用优势植物固土护坎等相应的对策。  相似文献   

The effect of conservation practices in sloped croplands on soil hydraulic properties and root‐zone moisture dynamics          下载免费PDF全文

Lirong Lin  Jiazhou Chen 《水文研究》2015,29(9):2079-2088

Rain‐induced erosion and short‐term drought are the two factors that limit the productivity of croplands in the red soil region of subtropical China. The objective of this study was to estimate the effects of conservation practices on hydraulic properties and root‐zone water dynamics of the soil. A 3‐year experiment was performed on a slope at Xianning. Four treatments were evaluated for their ability to reduce soil erosion and improve soil water conditions. Compared with no practices (CK) and living grass strips (GS), the application of polyacrylamide (PAM) significantly reduced soil crust formation during intense rainfall, whereas rice straw mulching (SM) completely abolished soil crust formation. The SM and PAM treatments improved soil water‐stable aggregates, with a redistribution of micro‐aggregates into macro‐aggregates. PAM and SM significantly increased the soil water‐holding capacity. These practices mitigated the degradation of the soil saturated hydraulic conductivity (Ks) during intense rainfalls. These methods increased soil water storage but with limited effects during heavy rainfalls in the wet period. In contrast, during the dry period, SM had the highest soil water storage, followed by PAM and CK. Grass strips had the lowest soil water storage because of the water uptake during the vigorous grass growth. A slight decline in the soil moisture resulted in a significant decrease in the unsaturated hydraulic conductivity (Ku) of the topsoil. Therefore, the hydraulic conductivity in the field is governed by soil moisture, and the remaining soil moisture is more important than improving soil properties to resist short‐term droughts. As a result, SM is the most effective management practice when compared with PAM and GS, although they all protect the soil hydraulic properties during wet periods. These results suggest that mulching is the best strategy for water management in erosion‐threatened and drought‐threatened red soils. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

Deciphering the impact of land-uses on terrestrial organic matter and mercury inputs to large boreal lakes of central Québec using lignin biomarkers     

《Applied Geochemistry》2014

To evaluate watershed impacts of anthropogenic activities on terrestrial organic matter (TOM) and total mercury (THg) dynamics in large boreal lake ecosystems, we studied sediment cores retrieved in eight large lakes of Québec (Canada). Two lakes with pristine watersheds were considered as reference lakes and six lakes with watersheds affected by different types of anthropogenic activities (e.g. logging and/or mining activities) were used to illustrate the influence of land-use on TOM and Hg cycling in lakes. A Geographical Information System (GIS) approach was used to correlate the evolution of anthropogenic land-uses from 1979 to 2010 (e.g. logging and mining activities) to TOM and THg contents measured in sediment cores. In each core, THg concentrations gradually increased over the recent years. Using lignin biomarkers, we noticed that the presence of both intense logging and mining activities in the watershed does not necessarily correspond to noticeable changes in the relative amount of terrestrial organic matter (TOM) exported from the watershed to the sediments and by extension to the level of THg measured in sediments. Apparently large-scale watersheds show some “buffering” capacity to land-use disturbance.  相似文献   

Sequestration of molybdate during transformation of 2-line ferrihydrite under alkaline conditions     

《Applied Geochemistry》2016

Hematite is a thermodynamically stable iron oxide under the aerobic conditions present in most natural surface soils and sediments. Most studies to date have focused on the capacity of hematite to adsorb trace metals and metalloids, but structural incorporation of trace metals within hematite is less recognized. This study assessed the incorporation of molybdenum within the structure of hematite during the phase transformation of 2-line ferrihydrite under alkaline conditions (pH ∼10). Extended X-ray absorption fine structure analyses show molybdenum incorporated into hematite, with two Mo-O shells having a coordination number (CN) of 3 and average bond distances of 1.78 ± 0.01 and 2.08 ± 0.02 Å, respectively, as well as two Mo-Fe shells with a CN of 3 and average bond distances of 3.10 ± 0.02 Å and 3.44 ± 0.02 Å, respectively. This observation suggests the tetrahedrally-coordinated Mo in the molybdate that adsorbs onto the 2-line ferrihydrite changes to an octahedrally-coordinated Mo within the hematite with Mo possibly substituting for Fe in the hematite structure. Our findings suggest that molybdenum partitioning (low concentrations) to iron oxides in the environment can occur due to structural incorporation as well as adsorption.  相似文献   

Assessing suitability of rural settlements using an improved technique for order preference by similarity to ideal solution   总被引：1，自引：1，他引：0  

Yanfang Liu  Jiaxing Cui  Xuesong Kong  Chen Zeng 《中国地理科学(英文版)》2016,26(5):638-655

Land suitability assessment is a prerequisite phase in land use planning; it guides toward optimal land use by providing information on the opportunities and constraints involved in the use of a given land area. A geographic information system-based procedure, known as rural settlement suitability evaluation (RSSE) using an improved technique for order preference by similarity to ideal solution (TOPSIS), was adopted to determine the most suitable area for constructing rural settlements in different geographical locations. Given the distribution and independence of rural settlements, a distinctive evaluation criteria system that differed from that of urban suitability was established by considering the level of rural infrastructure services as well as living and working conditions. The unpredictable mutual interference among evaluation factors has been found in practical works. An improved TOPSIS using Mahalanobis distance was applied to solve the unpredictable correlation among the criteria in a suitability evaluation. Uncertainty and sensitivity analyses obtained via Monte Carlo simulation were performed to examine the robustness of the model. Daye, a resource-based city with rapid economic development, unsatisfied rural development, and geological environmental problems caused by mining, was used as a case study. Results indicate the following findings: 1) The RSSE model using the improved TOPSIS can assess the suitability of rural settlements, and the suitability maps generated using the improved TOPSIS have higher information density than those generated using traditional TOPSIS. The robustness of the model is improved, and the uncertainty is reduced in the suitability results. 2) Highly suitable land is mainly distributed in the northeast of the study area, and the majority of which is cultivated land, thereby leading to tremendous pressure on the loss of cultivated land. 3) Lastly, 12.54% of the constructive expansion permitted zone and 8.36% of the constructive expansion conditionally permitted zone are situated in an unsuitable area, which indicates that the general planning of Daye lacks the necessary verification of suitability evaluation. Guidance is provided on the development strategy of rural settlement patches to support decision making in general land use planning.  相似文献   

三峡库区紫色土坡地养分状况及养分流失^*   总被引：33，自引：3，他引：33  

蔡崇法  丁树文 《地理研究》1996,15(3):77-84

紫色土是三峡库区移民安置区的主要坡地土壤。本研究采用典型区域调查,代表性土壤剖面养分分析,结合实验小区人工降雨的方法,初步研究了发育于侏罗纪紫色砂泥岩母质上紫色土的养分状况、养分流失特点、过程及影响养分流失因素。  相似文献   

Differences of granitic weathering at the northern and southern feet of Dabie Mountains,Central China: Implication for tectonic and climatic environments   总被引：2，自引：0，他引：2  

续海金  马昌前  刘凡  杨坤光 《中国科学D辑(英文版)》2003,46(7):641-651

Previous studies of weathering generally started with geochemistry[1—8] and mineralogy[9—12], and have been focused on chemical weathering rates[1—3], removability-enrichment of elements[3—6] during chemical weathering, and the age of weathering profi…  相似文献